The effect of indium(III) triflate in oxone-mediated oxidative methyl esterification of aldehydes

Chem Pharm Bull (Tokyo). 2013;61(8):870-2. doi: 10.1248/cpb.c13-00072.

Abstract

An oxidative methyl esterification of aldehydes was effectively achieved. The trivalent indium reagent, indium(III) triflate, was revealed to accelerate the reactions in many cases. Aromatic aldehydes with various substituents were subjected to this method, and each produced the corresponding methyl esters in good to excellent yields within a relatively short reaction time.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aldehydes / chemistry*
  • Esterification
  • Hydrocarbons, Aromatic / chemistry*
  • Mesylates / chemistry*
  • Methylation
  • Oxidation-Reduction
  • Sulfuric Acids / chemistry*

Substances

  • Aldehydes
  • Hydrocarbons, Aromatic
  • Mesylates
  • Sulfuric Acids
  • potassium peroxymonosulfuric acid
  • trifluoromethanesulfonic acid