Capillary breakup of discontinuously rate thickening suspensions

Phys Rev Lett. 2013 Jul 19;111(3):036001. doi: 10.1103/PhysRevLett.111.036001. Epub 2013 Jul 19.

Abstract

Using discontinuously rate thickening suspensions (DRTS) as a model system, we show that beads-on-a-string morphologies can arise as a result of external viscous drag acting during capillary-driven breakup of a non-Newtonian fluid. To minimize the perturbative effect of gravity, we developed a new experimental test platform in which the filament is supported in a horizontal position at the surface of an immiscible oil bath. We show that the evolution of thin DRTS filaments during the capillary thinning process is well described by a set of one-dimensional slender filament equations. The strongly rate-dependent rheology of the test fluid and the aspect ratio of the filament couple to control the thinning dynamics and lead to a simple criterion describing the localized arrest of the capillary thinning process and the subsequent formation of complex, high aspect ratio beads-on-a-string structures.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Corn Oil / chemistry
  • Models, Theoretical*
  • Polyethylene Glycols / chemistry
  • Polystyrenes / chemistry
  • Suspensions / chemistry*
  • Viscosity
  • Water / chemistry

Substances

  • Polystyrenes
  • Suspensions
  • Water
  • Polyethylene Glycols
  • Corn Oil