Abstract
Tetrathiafulvalenes (TTF)-annulated [28]hexaphyrin affords an electron rich flexible π-conjugated system whose limiting conformations can be controlled through choice of solvents. The conformation-dependent intramolecular charge transfer character, as well as electron reserve capability of the hexakis-TTF annulated hexaphyrin, was analyzed.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Crystallography, X-Ray
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Cyclization
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Electrochemical Techniques
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Electrons
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Heterocyclic Compounds / chemistry*
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Heterocyclic Compounds, 2-Ring / chemical synthesis
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Heterocyclic Compounds, 2-Ring / chemistry*
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Molecular Conformation
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Oxidation-Reduction
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Porphyrins / chemical synthesis
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Porphyrins / chemistry*
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Solvents / chemistry
Substances
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Heterocyclic Compounds
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Heterocyclic Compounds, 2-Ring
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Porphyrins
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Solvents
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tetrathiafulvalene