Synthesis and characterization of PEG-iron oxide core-shell composite nanoparticles for thermal therapy

Mater Sci Eng C Mater Biol Appl. 2013 Dec 1;33(8):4660-6. doi: 10.1016/j.msec.2013.07.019. Epub 2013 Jul 24.

Abstract

In this study, core-shell nanoparticles were developed to achieve thermal therapy that can ablate cancer cells in a remotely controlled manner. The core-shell nanoparticles were prepared using atomic transfer radical polymerization (ATRP) to coat iron oxide (Fe3O4) nanoparticles with a poly(ethylene glycol) (PEG) based polymer shell. The iron oxide core allows for the remote heating of the particles in an alternating magnetic field (AMF). The coating of iron oxide with PEG was verified through Fourier transform infrared spectroscopy and thermal gravimetric analysis. A thermoablation (55°C) study was performed on A549 lung carcinoma cells exposed to nanoparticles and over a 10 min AMF exposure. The successful thermoablation of A549 demonstrates the potential use of polymer coated particles for thermal therapy.

Keywords: Atom transfer radical polymerization; Magnetic nanoparticles; Thermal therapy.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Animals
  • Biocompatible Materials / chemical synthesis*
  • Biocompatible Materials / therapeutic use
  • Biocompatible Materials / toxicity
  • Cell Line, Tumor
  • Cell Survival / drug effects
  • Ferrosoferric Oxide / chemistry*
  • Humans
  • Hyperthermia, Induced
  • Lung Neoplasms / therapy
  • Magnetic Fields
  • Magnetite Nanoparticles / chemistry*
  • Magnetite Nanoparticles / toxicity
  • Mice
  • NIH 3T3 Cells
  • Polyethylene Glycols / chemistry*
  • Polymers / chemical synthesis
  • Polymers / chemistry*
  • Temperature

Substances

  • Biocompatible Materials
  • Magnetite Nanoparticles
  • Polymers
  • Polyethylene Glycols
  • Ferrosoferric Oxide