Highly concave platinum nanoframes with high-index facets and enhanced electrocatalytic properties

Angew Chem Int Ed Engl. 2013 Nov 18;52(47):12337-40. doi: 10.1002/anie.201307518. Epub 2013 Sep 25.

Abstract

Deeply excavated: Platinum nanoframes with highly concave {740} facets are synthesized directly by a facile oleylamine-assisted solvothermal method. Because of the unique structure and exposed high-index facets, the as-prepared Pt nanoframes exhibit very high electrocatalytic activity and remarkable stability for the oxygen reduction reaction and the oxidation of methanol and formic acid.

Keywords: concave surface; electrocatalysis; high-index facets; nanocrystals; platinum.