Absolute density measurement of SD radicals in a supersonic jet at the quantum-noise-limit

Phys Chem Chem Phys. 2013 Dec 7;15(45):19575-9. doi: 10.1039/c3cp53394h. Epub 2013 Oct 21.

Abstract

The absolute density of SD radicals in a supersonic jet has been measured down to (1.1 ± 0.1) × 10(5) cm(-3) in a modestly specified apparatus that uses a cross-correlated combination of cavity ring-down and laser-induced fluorescence detection. Such a density corresponds to 215 ± 21 molecules in the probe volume at any given time. The minimum detectable absorption coefficient was quantum-noise-limited and measured to be (7.9 ± 0.6) × 10(-11) cm(-1), in 200 s of acquisition time, corresponding to a noise-equivalent absorption sensitivity for the apparatus of (1.6 ± 0.1) × 10(-9) cm(-1) Hz(-1/2).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aircraft*
  • Free Radicals / chemistry*
  • Nitrogen / chemistry
  • Quantum Theory*
  • Spectrometry, Fluorescence

Substances

  • Free Radicals
  • Nitrogen