Morphology control of one dimension (1D) nanomaterials is a pivotal issue in the field of nanoscience research to exploit their novel properties. Herein, we report the morphology controlled synthesis of 1D β-Sialon nanowires, nanobelts and hierarchical nanostructures via a thermal-chemical vapour deposition process using an appropriately selected catalyst and optimized temperature schedule. Vapour-solid (VS), a combination of vapour-liquid-solid (VLS)-based and VS-tip, and a combination of VS for one-generation nanowires with nucleation, growth and coalescence of two-generation nanobranches (NGCB) are used to explain the growth of β-Sialon nanowires, nanobelts and hierarchical nanostructures, respectively. Cathodoluminescence measurements show that the individual β-Sialon 1D nanostructures with different morphologies have different luminescent properties. All nanostructures exhibit two distinct emission peaks, the violet/blue emission centered at ~390 nm (3.18 eV), attributable to the near band edge (NBE) emission, and the red emission centered at ~728 nm (1.70 eV), assigned to the deep level (DL) emission. However, the DL emission is the ruling emission in the case of an individual β-Sialon nanowire, whereas the NBE emission becomes dominant in the case of an individual nanobelt as well as a hierarchical nanostructure due to the size and surface effects. The as-synthesized β-Sialon with controlled nanostructures and various morphologies can find potential applications in future nanodevices with tailorable or tunable photoelectric properties.