Ammonia-in-oil-microemulsions and their application

Angew Chem Int Ed Engl. 2013 Nov 18;52(47):12443-7. doi: 10.1002/anie.201305289. Epub 2013 Sep 25.

Abstract

Liquid ammonia on the nanoscale: Ammonia-in-oil microemulsions are used to synthesize Bi, Re, CoN, and GaN nanoparticles, which can be obtained without further thermal treatment. These microemulsions are as reproducible and simple as their water-in-oil conterparts, with the exception of the required low temperature of -40 °C.

Keywords: liquid ammonia; metal nitrides; metals; microemulsions; nanoparticles.