Novel sodium intercalated (NH4)2V6O16 platelets: High performance cathode materials for lithium-ion battery

Hailong Fei; Xiaomin Wu; Huan Li; Mingdeng Wei

doi:10.1016/j.jcis.2013.10.025

Novel sodium intercalated (NH4)2V6O16 platelets: High performance cathode materials for lithium-ion battery

J Colloid Interface Sci. 2014 Feb 1:415:85-8. doi: 10.1016/j.jcis.2013.10.025. Epub 2013 Oct 24.

Authors

Hailong Fei¹, Xiaomin Wu, Huan Li, Mingdeng Wei

Affiliation

¹ Institute of Advanced Energy Materials, Fuzhou University, 523 Industry Road, Fuzhou 350002, PR China.

PMID: 24267333
DOI: 10.1016/j.jcis.2013.10.025

Abstract

A simple and versatile method for preparation of novel sodium intercalated (NH4)2V6O16 is developed via a simple hydrothermal route. It is found that ammonium sodium vanadium bronze displays higher discharge capacity and better rate cyclic stability than ammonium vanadium bronze as lithium-ion battery cathode material because of smaller charge transfer resistance, which would favor superior discharge capacity and rate performance.

Keywords: Ammonium metavanadate; Bi-cation; Cathode; Hydrothermal; Intercalation; Oxalic acid; Raman; Sodium nitrate; Sodium-ion battery; Vanadium bronze.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Electric Power Supplies*
Electricity
Electrodes
Green Chemistry Technology*
Nitrates / chemistry
Oxalic Acid / chemistry
Vanadates / chemistry

Substances

Nitrates
Vanadates
sodium nitrate
Oxalic Acid
ammonium metavanadate