Gellan hydrogel as a powerful tool in paper cleaning process: a detailed study

J Colloid Interface Sci. 2014 Feb 15:416:205-11. doi: 10.1016/j.jcis.2013.10.062. Epub 2013 Nov 8.

Abstract

Hypothesis: Wet cleaning of ancient papers is one of the most critical steps during a conservation treatment. It is used to improve the optical qualities of a graphic work and remove dust and by-products resulting from cellulose degradation. Nevertheless, washing treatment usually involves a substantial impact on the original morphological structure of paper and can sometimes be dangerous for water sensitive inks and pigments.

Experiments: The use of rigid hydrogel of Gellan gum as an alternative paper cleaning treatment is developed. The application of a rigid hydrogel minimizes damages caused by the use of water, and therefore is much more respectful for the original integrity of ancient paper.

Findings: Gellan hydrogel has been used to clean paper samples belonging to different centuries (from XVI to XIX) and therefore, characterized by a different story in terms of degradation condition and paper composition. Several techniques, such as high-performance liquid chromatography, Fourier transform infrared spectroscopy, scanning electron microscopy and pH measurements, has been employed to assess the effectiveness and safety of the proposed cleaning method.

Keywords: FTIR; Gel residues; Gellan gum; HPLC; Paper conservation; Paper morphology cultural heritage; SEM.

Publication types

  • Historical Article

MeSH terms

  • Chromatography, High Pressure Liquid
  • Green Chemistry Technology
  • History, 16th Century
  • History, 17th Century
  • History, 18th Century
  • History, 19th Century
  • Humans
  • Hydrogels
  • Hydrogen-Ion Concentration
  • Italy
  • Microscopy, Electron, Scanning
  • Paper / history*
  • Polysaccharides, Bacterial / chemistry*
  • Spectroscopy, Fourier Transform Infrared

Substances

  • Hydrogels
  • Polysaccharides, Bacterial
  • gellan gum