The directing effect of linking units on building microporous architecture in tetraphenyladmantane-based poly(Schiff base) networks

Guiyang Li; Biao Zhang; Jun Yan; Zhonggang Wang

doi:10.1039/c3cc48593e

The directing effect of linking units on building microporous architecture in tetraphenyladmantane-based poly(Schiff base) networks

Chem Commun (Camb). 2014 Feb 21;50(15):1897-9. doi: 10.1039/c3cc48593e. Epub 2014 Jan 9.

Authors

Guiyang Li¹, Biao Zhang, Jun Yan, Zhonggang Wang

Affiliation

¹ State Key Laboratory of Fine Chemicals, Department of Polymer Science and Materials, School of Chemical Engineering, Dalian University of Technology, Dalian, 116024, China. [email protected].

PMID: 24406818
DOI: 10.1039/c3cc48593e

Abstract

Tetraphenyladamantane-based porous poly(Schiff base)s with BET surface area (>1000 m(2) g(-1)), CO2 uptake (15 wt%, 273 K/1 bar) and H2 uptake (1.26 wt%, 77 K/1 bar) were synthesized. The structure-directing effect of isomers of phenyl diamines on building porous architecture was investigated.