Rifampicin-loaded 'flower-like' polymeric micelles for enhanced oral bioavailability in an extemporaneous liquid fixed-dose combination with isoniazid

Nanomedicine (Lond). 2014 Aug;9(11):1635-50. doi: 10.2217/nnm.13.154. Epub 2014 Jan 10.

Abstract

Background: Coadministration of rifampicin (RIF)/isoniazid (INH) is clinically recommended to improve the treatment of tuberculosis. Under gastric conditions, RIF undergoes fast hydrolysis (a pathway hastened by INH) and oral bioavailability loss.

Aim: We aimed to assess the chemical stabilization and the oral pharmacokinetics of RIF nanoencapsulated within poly(ε-caprolactone)-b-PEG-b-poly(ε-caprolactone) 'flower-like' polymeric micelles.

Materials & methods: The chemical stability of RIF was evaluated in vitro under acid conditions with and without INH, and the oral pharmacokinetics of RIF-loaded micelles in rats was compared with those of a suspension coded by the US Pharmacopeia.

Results: Nanoencapsulation decreased the degradation rate of RIF with respect to the free drug. Moreover, in vivo data showed a statistically significant increase of RIF oral bioavailability (up to 3.3-times) with respect to the free drug in the presence of INH.

Conclusion: Overall results highlight the potential of this nanotechnology platform to develop an extemporaneous liquid RIF/INH fixed-dose combination suitable for pediatric administration.

Keywords: extemporaneous liquid rifampicin/isoniazid fixed-dose combination; improved oral pharmacokinetics; pediatric tuberculosis; poly(ε-caprolactone)-b-PEG-b-poly(ε-caprolactone) ‘flower-like’ polymeric micelle; rifampicin chemical stabilization.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Administration, Oral
  • Animals
  • Antitubercular Agents / administration & dosage
  • Area Under Curve
  • Biological Availability
  • Chromatography, High Pressure Liquid
  • Drug Carriers / chemistry*
  • Ethylene Glycols / chemistry
  • Hydrochloric Acid / chemistry
  • Isoniazid / administration & dosage*
  • Male
  • Micelles
  • Nanomedicine
  • Particle Size
  • Polyesters / chemistry
  • Polymers / chemistry*
  • Rats
  • Rats, Wistar
  • Rifampin / administration & dosage*
  • Solubility
  • Tuberculosis / drug therapy

Substances

  • Antitubercular Agents
  • Drug Carriers
  • Ethylene Glycols
  • Micelles
  • Polyesters
  • Polymers
  • poly(epsilon-caprolactone)-b-poly(ethylene glycol)
  • lactide-caprolactone copolymer
  • Hydrochloric Acid
  • Isoniazid
  • Rifampin