Di-μ-tricyanido-tetra-cyanidobis[hydro-tris-(pyrazoylborato)]tetra-methanol-diiron(III)iron(II) di-methanol disolvate

Kuirun Zhang; Osamu Sato

doi:10.1107/S1600536814001019

Di-μ-tricyanido-tetra-cyanidobis[hydro-tris-(pyrazoylborato)]tetra-methanol-diiron(III)iron(II) di-methanol disolvate

Acta Crystallogr Sect E Struct Rep Online. 2014 Jan 22;70(Pt 2):m56. doi: 10.1107/S1600536814001019. eCollection 2014 Feb 1.

Authors

Kuirun Zhang¹, Osamu Sato¹

Affiliation

¹ Institute for Materials Chemistry and Engineering, Kyushu University, 6-1, Kasuga-koen, Fukuoka 816-0811, Japan.

Abstract

In the title complex, [Fe(II)Fe(III) 2(C9H10BN6)2(CN)6(CH3OH)4]·2CH3OH, two [Fe(III)(Tp)(CN)3](-) anions [Tp is hydro-tris-(pyrazoylborate)] are bridged by an [Fe(II)(MeOH)4](2+) cation, forming a centrosymmetric trinuclear unit. These units are connected via O-H⋯O and O-H⋯N hydrogen bonds involving the uncoordinated methanol solvent mol-ecules, forming a three-dimensional network.