Isolation of a keratinolytic proteinase from Trichophyton mentagrophytes with enzymatic activity at acidic pH

Infect Immun. 1989 Nov;57(11):3479-83. doi: 10.1128/iai.57.11.3479-3483.1989.

Abstract

A keratinolytic proteinase with enzyme activity at acidic pH was isolated from culture filtrates of Trichophyton mentagrophytes, a major pathogenic fungus of dermatophytosis. The molecular weight of the proteinase was estimated to be 41,000 by sodium dodecyl sulfate-polyacrylamide gel electrophoresis and 38,000 by gel filtration. The isoelectric point was determined to be 3.9. The proteinase had a pH optimum of 4.5 for keratin and 5.5 for hemoglobin. This enzyme hydrolyzed the synthetic chymotrypsin substrate Suc-Ala-Ala-Pro-Phe-MCA (Km, 0.59 mM), and its activity was strongly inhibited by chymostatin. Previously reported proteinases from dermatophytes have had enzyme activities in neutral or alkaline pH; however, healthy skin has a weakly acidic pH. Thus, the purified proteinase which has an optimal activity at acidic pH and hydrolyzes skin constituents could be an important virulence factor in dermatophytosis.

MeSH terms

  • Cations, Divalent / pharmacology
  • Extracellular Space / enzymology
  • Hydrogen-Ion Concentration
  • Isoelectric Point
  • Keratins / metabolism*
  • Kinetics
  • Molecular Weight
  • Peptide Hydrolases / isolation & purification*
  • Protease Inhibitors / pharmacology
  • Substrate Specificity
  • Tinea Pedis / microbiology
  • Trichophyton / enzymology*

Substances

  • Cations, Divalent
  • Protease Inhibitors
  • Keratins
  • Peptide Hydrolases