Immuno-chemotherapeutic platinum(IV) prodrugs of cisplatin as multimodal anticancer agents

Angew Chem Int Ed Engl. 2014 Jun 23;53(26):6752-6. doi: 10.1002/anie.201402879. Epub 2014 May 20.

Abstract

There is growing consensus that the clinical therapeutic efficacy of some chemotherapeutic agents depends on their off-target immune-modulating effects. Pt anticancer drugs have previously been identified to be potent immunomodulators of both the innate and the adaptive immune system. Nevertheless, there has been little development in the rational design of Pt-based chemotherapeutic agents to exploit their immune-activating capabilities. The FPR1/2 formyl peptide receptors are highly expressed in immune cells, as well as in many metastatic cancers. Herein, we report a rationally designed multimodal Pt(IV) prodrug containing a FPR1/2-targeting peptide that combines chemotherapy with immunotherapy to achieve therapeutic synergy and demonstrate the feasibility of this approach.

Keywords: antitumor agents; cisplatin; drug targeting; peptides; platinum.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Antineoplastic Agents / chemistry*
  • Antineoplastic Agents / toxicity
  • Cell Line, Tumor
  • Cell Survival / drug effects
  • Cisplatin / chemistry*
  • Cisplatin / toxicity
  • Coordination Complexes / chemistry
  • Coordination Complexes / toxicity
  • Humans
  • Immunity, Innate / drug effects
  • Killer Cells, Natural / drug effects
  • Killer Cells, Natural / immunology
  • MCF-7 Cells
  • Macrophages / drug effects
  • Macrophages / immunology
  • Platinum / chemistry*
  • Prodrugs / chemistry*
  • Prodrugs / toxicity
  • Receptors, Formyl Peptide / antagonists & inhibitors
  • Receptors, Formyl Peptide / metabolism
  • Receptors, Lipoxin / antagonists & inhibitors
  • Receptors, Lipoxin / metabolism

Substances

  • Antineoplastic Agents
  • Coordination Complexes
  • FPR1 protein, human
  • FPR2 protein, human
  • Prodrugs
  • Receptors, Formyl Peptide
  • Receptors, Lipoxin
  • Platinum
  • Cisplatin