Maslinic acid modulates glycogen metabolism by enhancing the insulin signaling pathway and inhibiting glycogen phosphorylase

Chin J Nat Med. 2014 Apr;12(4):259-65. doi: 10.1016/S1875-5364(14)60052-2.

Abstract

Aim: To investigate the molecular signaling mechanism by which the plant-derived, pentacyclic triterpene maslinic acid (MA) exerts anti-diabetic effects.

Method: HepG2 cells were stimulated with various concentrations of MA. The effects of MA on glycogen phosphorylase a (GPa) activity and the cellular glycogen content were measured. Western blot analyses were performed with anti-insulin receptor β (IRβ), protein kinase B (also known as Akt), and glycogen synthase kinase-3β (GSK3β) antibodies. Activation status of the insulin pathway was investigated using phospho-IRβ, as well as phospho-Akt, and phospho-GSK3β antibodies. The specific PI3-kinase inhibitor wortmannin was added to the cells to analyze the Akt expression. Enzyme-linked immunosorbent assay (ELISA) was used to measure the effect of MA on IRβ auto-phosphorylation. Furthermore, the effect of MA on glycogen metabolism was investigated in C57BL/6J mice fed with a high-fat diet (HFD).

Results: The results showed that MA exerts anti-diabetic effects by increasing glycogen content and inhibiting glycogen phosphorylase activity in HepG2 cells. Furthermore, MA was shown to induce the phosphorylation level of IRβ-subunit, Akt, and GSK3β. The MA-induced activation of Akt appeared to be specific, since it could be blocked by wortmannin. Finally, MA treatment of mice fed with a high-fat diet reduced the model-associated adiposity and insulin resistance, and increased the accumulated hepatic glycogen content.

Conclusion: The results suggested that maslinic acid modulates glycogen metabolism by enhancing the insulin signaling pathway and inhibiting glycogen phosphorylase.

Keywords: Glycogen metabolism; Glycogen phosphorylation a; Insulin signal transduction; Maslinic acid.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Diabetes Mellitus / drug therapy*
  • Diabetes Mellitus / enzymology
  • Diabetes Mellitus / genetics
  • Diabetes Mellitus / metabolism*
  • Drugs, Chinese Herbal / administration & dosage*
  • Enzyme Inhibitors / administration & dosage
  • Glycogen / metabolism*
  • Glycogen Phosphorylase / antagonists & inhibitors*
  • Glycogen Phosphorylase / genetics
  • Glycogen Phosphorylase / metabolism
  • Hep G2 Cells
  • Humans
  • Insulin / metabolism*
  • Male
  • Mice
  • Mice, Inbred C57BL
  • Signal Transduction / drug effects
  • Triterpenes / administration & dosage*

Substances

  • Drugs, Chinese Herbal
  • Enzyme Inhibitors
  • Insulin
  • Triterpenes
  • Glycogen
  • maslinic acid
  • Glycogen Phosphorylase