A 3D aluminoborate open framework interpenetrated by 2D zinc-amine coordination-polymer networks in its 11-ring channels

Li Wei; Qi Wei; Zhi-En Lin; Qin Meng; Huan He; Bai-Feng Yang; Guo-Yu Yang

doi:10.1002/anie.201402663

A 3D aluminoborate open framework interpenetrated by 2D zinc-amine coordination-polymer networks in its 11-ring channels

Angew Chem Int Ed Engl. 2014 Jul 7;53(28):7188-91. doi: 10.1002/anie.201402663. Epub 2014 May 30.

Authors

Li Wei¹, Qi Wei, Zhi-En Lin, Qin Meng, Huan He, Bai-Feng Yang, Guo-Yu Yang

Affiliation

¹ MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing 100081 (China).

PMID: 24890739
DOI: 10.1002/anie.201402663

Abstract

A new inorganic-organic hybrid solid, [Zn(dap)2 ][AlB5 O10 ], combining the structural features of 3D open-framework inorganic solids and 2D metal-organic coordination polymers has been synthesized under solvothermal conditions. The compound displays extensive luminescence and moderate second-harmonic-generation efficiency.

Keywords: aluminoborates; coordination polymers; open frameworks; organic-inorganic hybrid composites; supramolecular templates.