Coating two-dimensional nanomaterials with metal-organic frameworks

ACS Nano. 2014 Aug 26;8(8):8695-701. doi: 10.1021/nn503834u. Epub 2014 Aug 4.

Abstract

We demonstrate the coating of various 2D nanomaterials including MoS2 nanosheets, graphene oxide (GO), and reduced graphene oxide (rGO) with zeolitic imidazolate frameworks (i.e., ZIF-8) via a facile procedure. Additionally, ternary core-shell structures like Pt-MoS2@ZIF-8, Pt-GO@ZIF-8, and Pt-rGO@ZIF-8 have also been prepared. As a proof-of-concept application, a memory device based on MoS2@ZIF-8 hybrid was fabricated and it exhibited write-once-read-many-times (WORM) memory effect with high ON/OFF ratio and long operating lifetime. It is expected that MOF coated 2D nanomaterials may find wide applications in energy storage and conversion, catalysis, sensing, and information storage devices.

Publication types

  • Research Support, Non-U.S. Gov't