Temperature-programmed technique accompanied with high-throughput methodology for rapidly searching the optimal operating temperature of MOX gas sensors

ACS Comb Sci. 2014 Sep 8;16(9):459-65. doi: 10.1021/co500054r. Epub 2014 Aug 12.

Abstract

A combinatorial high-throughput temperature-programmed method to obtain the optimal operating temperature (OOT) of gas sensor materials is demonstrated here for the first time. A material library consisting of SnO2, ZnO, WO3, and In2O3 sensor films was fabricated by screen printing. Temperature-dependent conductivity curves were obtained by scanning this gas sensor library from 300 to 700 K in different atmospheres (dry air, formaldehyde, carbon monoxide, nitrogen dioxide, toluene and ammonia), giving the OOT of each sensor formulation as a function of the carrier and analyte gases. A comparative study of the temperature-programmed method and a conventional method showed good agreement in measured OOT.

Keywords: arrays; gas sensor; high-throughput screening; isothermal technique; oxide materials; temperature-dependent conductivity.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Ammonia / analysis
  • Atmosphere / analysis*
  • Atmosphere / chemistry*
  • Carbon Monoxide / analysis
  • Formaldehyde / analysis
  • Gases / analysis*
  • High-Throughput Screening Assays*
  • Indium / chemistry
  • Nitrogen Dioxide / analysis
  • Oxides / chemistry*
  • Particle Size
  • Surface Properties
  • Temperature*
  • Tin / chemistry
  • Toluene / analysis
  • Tungsten / chemistry
  • Zinc / chemistry

Substances

  • Gases
  • Oxides
  • Indium
  • Formaldehyde
  • Toluene
  • Tin
  • Ammonia
  • Carbon Monoxide
  • Zinc
  • Nitrogen Dioxide
  • Tungsten