A hybrid polyoxometalate-organic molecular catalyst for visible light driven water oxidation

C Zhang; X Lin; Z Zhang; L-S Long; C Wang; W Lin

doi:10.1039/c4cc03487b

A hybrid polyoxometalate-organic molecular catalyst for visible light driven water oxidation

Chem Commun (Camb). 2014 Oct 9;50(78):11591-4. doi: 10.1039/c4cc03487b.

Authors

C Zhang¹, X Lin, Z Zhang, L-S Long, C Wang, W Lin

Affiliation

¹ Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China.

PMID: 25141077
DOI: 10.1039/c4cc03487b

Abstract

A novel organic-inorganic hybrid monocapped/bicapped Keggin structure [Co(II)(bpy)3]6(H2bpy)[(Co(II)bpy)2(PMo8(VI)Mo4(V)O40)]3 [(Co(II)bpy)(PMo8(VI)Mo4(V)O40)]·16H2O (bpy = 2,2'-bipyridine) was synthesized and shown to be an efficient visible light-driven catalyst for water oxidation.