Large scale synthesis of graphene quantum dots (GQDs) from waste biomass and their use as an efficient and selective photoluminescence on-off-on probe for Ag(+) ions

Nanoscale. 2014 Oct 21;6(20):11664-70. doi: 10.1039/c4nr02494j. Epub 2014 Aug 27.

Abstract

Graphene quantum dots (GQDs) are synthesized from bio-waste and are further modified to produce amine-terminated GQDs (Am-GQDs) which have higher dispersibility and photoluminescence intensity than those of GQDs. A strong fluorescence quenching of Am-GQDs (switch-off) is observed for a number of metal ions, but only for the Ag(+) ions is the original fluorescence regenerated (switch-on) upon addition of L-cysteine.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biomass
  • Carbon / chemistry
  • Cysteine / chemistry
  • Fluorescent Dyes / chemistry
  • Gold / chemistry*
  • Graphite / chemistry*
  • Hydrogen Bonding
  • Ions
  • Luminescence
  • Metals / chemistry
  • Microscopy, Atomic Force
  • Microscopy, Electron, Transmission
  • Nanostructures / chemistry
  • Photochemistry*
  • Plant Leaves
  • Porosity
  • Quantum Dots*
  • Spectrometry, Fluorescence*
  • Spectrophotometry, Ultraviolet

Substances

  • Fluorescent Dyes
  • Ions
  • Metals
  • Carbon
  • Gold
  • Graphite
  • Cysteine