Abstract
A clear rationalization of the origin of chirality transfer from an optically active diol guest to an achiral Mg(ii)bisporphyrin host in a series of 1 : 2 host-guest supramolecular complexes has been reported here that has so far remained the most outstanding issue for the chirogenic process.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alcohols / chemistry*
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Hydrogen Bonding
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Macromolecular Substances / chemical synthesis
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Macromolecular Substances / chemistry
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Magnesium / chemistry*
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Metalloporphyrins / chemistry*
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Models, Molecular
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Molecular Conformation
Substances
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Alcohols
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Macromolecular Substances
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Metalloporphyrins
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Magnesium