Oxygen bubble-templated hierarchical porous ε-MnO2 as a superior catalyst for rechargeable Li-O2 batteries

Small. 2015 Feb 18;11(7):809-13. doi: 10.1002/smll.201401790. Epub 2014 Oct 2.

Abstract

Nickel foam-supported ε-MnO2 is synthesized through an oxygen-bubble template-assisted electrodeposition route and is applied as a new cathode catalyst for Li-O2 batteries. Owing to the 3D macro/micro/nano (multiscale) porous architecture, the prepared electrode exhibits low overpotential, high rate capability, and superior cycling durability.

Keywords: electrodeposition; lithium-oxygen batteries; manganese oxide; oxygen-bubble templates; porous structures.