The direct introduction of fluorine and fluorinated building blocks has recently attracted a lot of attention and particularly the direct functionalization of alkenes and alkynes. This review will highlight the major progress recently made in that field, with a focus on photocatalyzed transformations, base-promoted processes, and transition metal-catalyzed functionalization of alkenes and alkynes. Special attention will be paid to explanations of the reaction mechanisms.
Keywords: alkenes; alkynes; fluorination; radical reactions; trifluoromethylation.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.