Copper-mediated α-trifluoromethylation of N-phenylcinnamamides coupled with dearomatization: access to trifluoromethylated 1-azaspiro[4.5]decanes

Org Lett. 2014 Nov 21;16(22):5914-7. doi: 10.1021/ol502921a. Epub 2014 Nov 4.

Abstract

Copper-mediated intramolecular trifluoromethylation of N-phenylcinnamamides coupled with cyclization and dearomatization was used to construct various trifluoromethylated 1-azaspiro[4.5]decanes in moderate to high yields and with excellent regioselectivity and diastereoselectivity.

Publication types

  • Research Support, Non-U.S. Gov't