Promising biological monitoring for occupational 1,2-Dichloropropane exposure by urinalysis for unmetabolized solvent

J Occup Health. 2015;57(2):197-9. doi: 10.1539/joh.14-0234-OA. Epub 2015 Jan 20.

Abstract

Objectives: The aim of this study was to examine the applicability of urinalysis for unmetabolized solvent to biomonitor 1,2-dichloropropane (1,2-DCP) exposure.

Methods: Thirty three male printers exposed to 1,2-DCP and 5 nonexposed male controls participated in the study. The 8-hr average levels of exposure to 1,2-DCP in air and 1,2-DCP in the end-of-shift urine samples were measured with capillary FID-GC.

Results: The geometric mean (the maximum) concentrations was 7.1 ppm (23.1 ppm) for 1,2-DCP in air, and the level in urine (without correction for urine density) was 77 µg/l (247 µg/l). A regression analysis showed a correlation coefficient of 0.909 (p<0.01). No 1,2-DCP was detected in the urine samples from nonexposed subjects.

Conclusions: The high correlation and low background (essentially zero) showed that urinalysis for unmetabolized 1,2-DCP is a promising tool for biomonitoring of occupational exposure to this carcinogenic solvent at lower levels (e.g. <1 ppm).

MeSH terms

  • Adult
  • Air Pollutants, Occupational / urine*
  • Biomarkers / urine
  • Environmental Monitoring / methods*
  • Humans
  • Male
  • Middle Aged
  • Occupational Exposure*
  • Printing*
  • Propane / analogs & derivatives*
  • Propane / urine
  • Regression Analysis

Substances

  • Air Pollutants, Occupational
  • Biomarkers
  • propylene dichloride
  • Propane