Aqueous microwave-assisted cross-coupling reactions applied to unprotected nucleosides

Front Chem. 2015 Feb 17:3:10. doi: 10.3389/fchem.2015.00010. eCollection 2015.

Abstract

Metal catalyzed cross-coupling reactions have been the preferred tools to access to modified nucleosides (on the C5-position of pyrimidines and on the C7- or C8-positions of purines). Our objective is to focus this mini-review on the Suzuki-Miyaura and on the Heck cross-couplings of nucleosides using microwave irradiations which is an alternative technology compatible with green chemistry and sustainable development.

Keywords: Heck; Suzuki-Miyaura; green chemistry; microwave; nucleoside; nucleotide; water.

Publication types

  • Review