Estimation of bonding nature using diamagnetic susceptibility

Chem Commun (Camb). 2015 May 21;51(41):8691-4. doi: 10.1039/c5cc02351c.

Abstract

A chemical bond includes both covalent and ionic characteristics. We develop an experimental method to estimate the degree of each contribution based on magnetic susceptibility measurements, in which Pascal's scheme for Larmor diamagnetism is combined with electronegativity. The applicability to metal hydrides is also shown.