A Solvent-free Approach to Glycosyl Amides: Towards the Synthesis of α- N-Galactosyl Ceramides

Tetrahedron Lett. 2015 Jun 3;56(23):3583-3586. doi: 10.1016/j.tetlet.2015.02.133.

Abstract

A new, simple and efficient method for the synthesis of both α- and β-glycosyl amides using solvent-free conditions is described. This method involves the coupling of glycosyl amines with the p-nitrophenol esters of lipids as a key step.

Keywords: glycolipids; glycosyl amides; iNKT cells; solvent-free.