NMR structural characterization of the N-terminal active domain of the gyrase B subunit from Pseudomonas aeruginosa and its complex with an inhibitor

FEBS Lett. 2015 Sep 14;589(19 Pt B):2683-9. doi: 10.1016/j.febslet.2015.07.044. Epub 2015 Aug 10.

Abstract

The N-terminal ATP binding domain of the DNA gyrase B subunit is a validated drug target for antibacterial drug discovery. Structural information for this domain (pGyrB) from Pseudomonas aeruginosa is still missing. In this study, the interaction between pGyrB and a bis-pyridylurea inhibitor was characterized using several biophysical methods. We further carried out structural analysis of pGyrB using NMR spectroscopy. The secondary structures of free and inhibitor bound pGyrB were obtained based on backbone chemical shift assignment. Chemical shift perturbation and NOE experiments demonstrated that the inhibitor binds to the ATP binding pocket. The results of this study will be helpful for drug development targeting P. aeruginosa.

Keywords: Drug discovery; Gyrase B; NMR; Structure-based drug design; Topoisomerase.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adenosine Triphosphate / metabolism
  • Amino Acid Sequence
  • Catalytic Domain*
  • DNA Gyrase / chemistry*
  • DNA Gyrase / metabolism*
  • Models, Molecular
  • Molecular Sequence Data
  • Nuclear Magnetic Resonance, Biomolecular
  • Protein Binding
  • Pseudomonas aeruginosa / enzymology*
  • Topoisomerase II Inhibitors / chemistry
  • Topoisomerase II Inhibitors / metabolism*
  • Topoisomerase II Inhibitors / pharmacology
  • Urea / chemistry
  • Urea / metabolism
  • Urea / pharmacology

Substances

  • Topoisomerase II Inhibitors
  • Adenosine Triphosphate
  • Urea
  • DNA Gyrase