Is it worth carrying out determination of N-butane in postmortem samples? A case report and a comprehensive review of the literature

Int J Legal Med. 2016 Sep;130(5):1223-9. doi: 10.1007/s00414-015-1260-9. Epub 2015 Sep 12.

Abstract

The aim of this article is to illustrate the importance of N-butane determination in postmortem samples through a case report and to propose actions and precautions to be taken into consideration when butane is suspected to be involved in cases of death. The case concerns a 15-year-old boy found dead after sniffing a cigarette lighter refill. Toxicological investigation revealed the presence of butane in the heart and femoral blood (1280 and 1170 μg/L, respectively), in the gastric contents (326 μg/L), and in the liver (1010 μg/kg) and lung tissues (210 μg/kg). Propane was present only in the blood samples at concentrations tenfolds lower.Butane can be involved in three kinds of fatalities: deliberate inhalations including volatile substance abuse (VSA), involuntary exposure, and homicides. A fatal outcome of butane inhalation can be caused by asphyxia and/or cardiac arrhythmia. In the context where butane exposure is evidenced by non-toxicological investigations, the usefulness of the determination of butane in postmortem samples is often questionable. However, it is admitted that butane-related deaths are generally underreported. Several difficulties including sample handling and storage, substantial variation in tissue concentrations, and lack of a lethal threshold make the interpretation of butane results challenging. In our opinion, systematic toxicological methods should be developed in order to analyze butane, at least when it concerns a typical VSA victim, even when butane is not actually suspected to be the cause of death.

Keywords: Butane; Sudden death syndrome; Volatile substance abuse.

Publication types

  • Case Reports
  • Review

MeSH terms

  • Adolescent
  • Butanes / analysis*
  • Butanes / poisoning*
  • Chromatography, Liquid
  • Death, Sudden / etiology
  • Forensic Toxicology
  • Humans
  • Inhalant Abuse*
  • Male
  • Mass Spectrometry
  • Propane / blood

Substances

  • Butanes
  • butane
  • Propane