Accessing stable zirconium carboxy-aminophosphonate nanosheets as support for highly active Pd nanoparticles

Chem Commun (Camb). 2015 Nov 14;51(88):15990-3. doi: 10.1039/c5cc06292f. Epub 2015 Sep 18.

Abstract

Thin nanosheets from a layered zirconium phosphate-carboxyphosphonate is reported here. Small Pd nanoparticles have been supported on these nanosheets by an efficient method. The resulting Pd-catalyst was fully characterized and tested in the Suzuki-Miyaura coupling. The catalytic system proved its efficiency as it was reused for several cycles and showed low Pd leaching.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetates / chemistry
  • Biphenyl Compounds / chemical synthesis
  • Catalysis
  • Glycine / analogs & derivatives*
  • Glycine / chemistry
  • Ion Exchange
  • Metal Nanoparticles / chemistry*
  • Organometallic Compounds / chemistry
  • Organophosphorus Compounds / chemistry*
  • Zirconium / chemistry*

Substances

  • Acetates
  • Biphenyl Compounds
  • Organometallic Compounds
  • Organophosphorus Compounds
  • palladium(II) acetate
  • zirconium phosphate
  • glyphosphine
  • Zirconium
  • Glycine