Factors Impacting Electron Transfer in Cyano-Bridged {Fe2Co2} Clusters

Chunyang Zheng; Juping Xu; Zhixin Yang; Jun Tao; Dongfeng Li

doi:10.1021/acs.inorgchem.5b02272

Factors Impacting Electron Transfer in Cyano-Bridged {Fe2Co2} Clusters

Inorg Chem. 2015 Oct 19;54(20):9687-9. doi: 10.1021/acs.inorgchem.5b02272. Epub 2015 Oct 8.

Authors

Chunyang Zheng¹, Juping Xu¹, Zhixin Yang¹, Jun Tao², Dongfeng Li^{1

2}

Affiliations

¹ College of Chemistry, Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, Central China Normal University , 430079 Wuhan, P. R. China.
² State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University , Xiamen 361005, P. R. China.

PMID: 26447552
DOI: 10.1021/acs.inorgchem.5b02272

Abstract

A cyano-bridged {Fe(III)2Co(II)2} complex exhibits reversible thermally and photoinduced intramolecular charge transfer. Its desolvated, MeOH-d4, and other analogues were compared to disclose the impact factors on the electron-transfer behavior of these {Fe(III)2Co(II)2} clusters.