Abstract
Metal-organic frameworks (MOFs) based purely on sodium are rare, typically due to large numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker with flexible carboxylate groups to enhance framework stability. We report two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Adsorption
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Aspartic Acid / analogs & derivatives*
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Aspartic Acid / chemistry*
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Carbon Dioxide / chemistry
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Methanol / chemistry
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Molecular Structure
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry
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Oxides / chemistry
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Porosity
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Sodium Compounds / chemistry
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Solvents
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Stereoisomerism
Substances
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Organometallic Compounds
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Oxides
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Sodium Compounds
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Solvents
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Carbon Dioxide
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sodium oxide
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Aspartic Acid
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Methanol