Croconaine rotaxane for acid activated photothermal heating and ratiometric photoacoustic imaging of acidic pH

Chem Commun (Camb). 2016 Jan 4;52(1):120-3. doi: 10.1039/c5cc08317f.

Abstract

Absorption of 808 nm laser light by liposomes containing a pH sensitive, near-infrared croconaine rotaxane dye increases dramatically in weak acid. A stealth liposome composition permits acid activated, photothermal heating and also acts as an effective nanoparticle probe for ratiometric photoacoustic imaging of acidic pH in deep sample locations, including a living mouse.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acids / chemistry
  • Animals
  • Coloring Agents / chemistry*
  • Heating
  • Hydrogen-Ion Concentration
  • Light
  • Liposomes / chemistry
  • Mice
  • Nanoparticles / chemistry*
  • Photoacoustic Techniques / methods*
  • Photochemical Processes*
  • Rotaxanes / chemistry*
  • Spectrophotometry, Ultraviolet

Substances

  • Acids
  • Coloring Agents
  • Liposomes
  • Rotaxanes