The cardioprotective compound cloxyquin uncouples mitochondria and induces autophagy

Am J Physiol Heart Circ Physiol. 2016 Jan 1;310(1):H29-38. doi: 10.1152/ajpheart.00926.2014. Epub 2015 Oct 30.

Abstract

Mitochondrial quality control mechanisms have been implicated in protection against cardiac ischemia-reperfusion (IR) injury. Previously, cloxyquin (5-chloroquinolin-8-ol) was identified via phenotypic screening as a cardioprotective compound. Herein, cloxyquin was identified as a mitochondrial uncoupler in both isolated heart mitochondria and adult cardiomyocytes. Additionally, cardiomyocytes isolated from transgenic mice expressing green fluorescent protein-tagged microtubule-associated protein light chain 3 showed increased autophagosome formation with cloxyquin treatment. The autophagy inhibitor chloroquine abolished cloxyquin-induced cardioprotection in both cellular and perfused heart (Langendorff) models of IR injury. Finally, in an in vivo murine left anterior descending coronary artery occlusion model of IR injury, cloxyquin significantly reduced infarct size from 31.4 ± 3.4% to 16.1 ± 2.2%. In conclusion, the cardioprotective compound cloxyquin simultaneously uncoupled mitochondria and induced autophagy. Importantly, autophagy appears to be required for cloxyquin-induced cardioprotection.

Keywords: 8-hydroxyquinoline; heart; ischemia; mitophagy; uncoupling.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Animals
  • Autophagy / drug effects*
  • Chloroquine / pharmacology
  • Chloroquinolinols / pharmacology*
  • Dose-Response Relationship, Drug
  • Green Fluorescent Proteins / genetics
  • Green Fluorescent Proteins / metabolism
  • Isolated Heart Preparation
  • Male
  • Mice, Inbred C57BL
  • Mice, Transgenic
  • Microtubule-Associated Proteins / genetics
  • Microtubule-Associated Proteins / metabolism
  • Mitochondria, Heart / drug effects*
  • Mitochondria, Heart / metabolism
  • Mitochondria, Heart / pathology
  • Myocardial Infarction / metabolism
  • Myocardial Infarction / pathology
  • Myocardial Infarction / prevention & control*
  • Myocardial Reperfusion Injury / metabolism
  • Myocardial Reperfusion Injury / pathology
  • Myocardial Reperfusion Injury / prevention & control*
  • Myocytes, Cardiac / drug effects*
  • Myocytes, Cardiac / metabolism
  • Myocytes, Cardiac / pathology
  • Protective Agents / pharmacology*
  • Recombinant Fusion Proteins / metabolism
  • Time Factors
  • Uncoupling Agents / pharmacology*

Substances

  • Chloroquinolinols
  • Microtubule-Associated Proteins
  • Protective Agents
  • Recombinant Fusion Proteins
  • Uncoupling Agents
  • Green Fluorescent Proteins
  • Chloroquine
  • cloxyquin