Linear-noise approximation and the chemical master equation agree up to second-order moments for a class of chemical systems

Phys Rev E Stat Nonlin Soft Matter Phys. 2015 Oct;92(4):042124. doi: 10.1103/PhysRevE.92.042124. Epub 2015 Oct 12.

Abstract

It is well known that the linear-noise approximation (LNA) agrees with the chemical master equation, up to second-order moments, for chemical systems composed of zero and first-order reactions. Here we show that this is also a property of the LNA for a subset of chemical systems with second-order reactions. This agreement is independent of the number of interacting molecules.

MeSH terms

  • Kinetics
  • Linear Models
  • Models, Chemical*