Thermo-optical properties and nonlinear optical response of smectic liquid crystals containing gold nanoparticles

Phys Rev E Stat Nonlin Soft Matter Phys. 2015 Oct;92(4):042504. doi: 10.1103/PhysRevE.92.042504. Epub 2015 Oct 15.

Abstract

The present work is devoted to the study of the thermo-optical and nonlinear optical properties of smectic samples containing gold nanoparticles with different shapes. By using the time-resolved Z-scan technique, we determine the effects of nanoparticle addition on the critical behavior of the thermal diffusivity and thermo-optical coefficient at the vicinity of the smectic-A-nematic phase transition. Our results reveal that introduction of gold nanoparticles affects the temperature dependence of thermo-optical parameters, due to the local distortions in the orientational order and heat generation provided by guest particles during the laser exposure. Further, we show that a nonlinear optical response may take place at temperatures where the smectic order is well established. We provide a detailed discussion of the effects associated with the introduction gold nanoparticles on the mechanisms behind the thermal transport and optical nonlinearity in liquid-crystal samples.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Gold / chemistry*
  • Liquid Crystals / chemistry*
  • Metal Nanoparticles / chemistry*
  • Nonlinear Dynamics*
  • Optical Phenomena*
  • Phase Transition
  • Temperature*

Substances

  • Gold