A Conserved Inhibitory Mechanism of a Lycorine Derivative against Enterovirus and Hepatitis C Virus

Antimicrob Agents Chemother. 2015 Nov 23;60(2):913-24. doi: 10.1128/AAC.02274-15. Print 2016 Feb.

Abstract

Enterovirus 71 (EV71) (Picornaviridae family) and hepatitis C virus (HCV) (Flaviviridae family) are the causative agents of human hand, foot, and mouth disease (HFMD) and hepatitis C, resulting in a severe pandemic involving millions of infections in the Asia-Pacific region and worldwide. The great impact of EV71 and HCV on public health highlights the need to further our understanding of the biology of these two viruses and develop effective therapeutic antivirals. Here, we evaluated a total of 32 lycorine derivatives and demonstrated that 1-acetyllycorine suppressed the proliferation of multiple strains of EV71 in various cells. The results of the drug resistance analysis revealed that 1-acetyllycorine targeted a phenylalanine (F76) in EV71 2A protease (2A(pro)) to stabilize the conformation of a unique zinc finger. Most interestingly, the zinc binding site in EV71 2A(pro) is the exclusive homolog of HCV NS3 among all viruses. Further analysis revealed that 1-acetyllycorine also inhibits HCV with high efficacy, and the mutation on R118 in HCV NS3, which corresponds to F76 in EV71 2A(pro), confers the resistance of HCV to 1-acetyllycorine. These results revealed a conserved mechanism of 1-acetyllycorine against EV71 and HCV through targeting viral proteases. We also documented the significant synergistic anti-EV71 and anti-HCV effects of 1-acetyllycorine with reported inhibitors, supporting potential combination therapy for the treatment of EV71 and HCV infections.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amaryllidaceae Alkaloids / chemistry*
  • Amaryllidaceae Alkaloids / pharmacology
  • Animals
  • Antiviral Agents / chemistry
  • Antiviral Agents / pharmacology*
  • Cell Line
  • Drug Interactions
  • Drug Resistance, Viral / drug effects
  • Drug Resistance, Viral / genetics*
  • Enterovirus A, Human / drug effects*
  • Enterovirus A, Human / genetics
  • Hepacivirus / drug effects*
  • Hepacivirus / genetics
  • Humans
  • Mutation
  • Phenanthridines / chemistry*
  • Phenanthridines / pharmacology
  • Structural Homology, Protein
  • Viral Nonstructural Proteins / chemistry
  • Virus Replication / drug effects

Substances

  • 1-acetyllycorine
  • Amaryllidaceae Alkaloids
  • Antiviral Agents
  • NS3 protein, hepatitis C virus
  • Phenanthridines
  • Viral Nonstructural Proteins
  • lycorine

Grants and funding

This work was supported by the National Natural Science Foundation of China (grants 81322023, 31370733, 31170678, 31100208, 31000332, and 21202087), the National Basic Research Program of China (973 program) (grants 2013CB911100 and 2014CB542800), and Tsinghua University Initiative Scientific Research Program (2009THZ01).