Enantiopure anion templated synthesis of a zeolitic metal-organic framework

Zhong-Xuan Xu; Yu-Lu Ma; Jian Zhang

doi:10.1039/c5cc09308b

Enantiopure anion templated synthesis of a zeolitic metal-organic framework

Chem Commun (Camb). 2016 Jan 31;52(9):1923-5. doi: 10.1039/c5cc09308b.

Authors

Zhong-Xuan Xu¹, Yu-Lu Ma², Jian Zhang³

Affiliations

¹ State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. [email protected] and Department of Chemistry, Zunyi Normal College, Zunyi, Guizhou 563002, P. R. China.
² School of Chemical Science and Technology, Ynnan University, Kunming, 650091, P. R. China.
³ State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. [email protected].

PMID: 26680998
DOI: 10.1039/c5cc09308b

Abstract

Utilizing (R)-H3CIA as a chiral template, an unprecedented homochiral metal-organic framework (MOF) with zeotype GIS topology is obtained from achiral 1.4-DIB ligands and Zn(II) ions, which opens up a feasible approach to create zeolitic MOFs with homochirality.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Circular Dichroism
Ligands
Metals / chemistry*
Organic Chemicals / chemistry*
Proton Magnetic Resonance Spectroscopy
Stereoisomerism
Zeolites / chemistry*

Substances

Ligands
Metals
Organic Chemicals
Zeolites