Abstract
Utilizing (R)-H3CIA as a chiral template, an unprecedented homochiral metal-organic framework (MOF) with zeotype GIS topology is obtained from achiral 1.4-DIB ligands and Zn(II) ions, which opens up a feasible approach to create zeolitic MOFs with homochirality.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Circular Dichroism
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Ligands
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Metals / chemistry*
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Organic Chemicals / chemistry*
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Proton Magnetic Resonance Spectroscopy
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Stereoisomerism
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Zeolites / chemistry*
Substances
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Ligands
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Metals
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Organic Chemicals
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Zeolites