Reversible Effects of Peptide Concentration and Lipid Composition on H-Ras Lipid Anchor Clustering

Biophys J. 2015 Dec 15;109(12):2467-2470. doi: 10.1016/j.bpj.2015.11.009.

Abstract

Dynamic clusters of lipid-anchored Ras proteins are important for high-fidelity signal transduction in cells. The average size of Ras nanoclusters was reported to be independent of protein expression levels, and cholesterol depletion is commonly used to test the raft-preference of nanoclusters. However, whether protein concentration and membrane domain stability affect Ras clustering in a reversible manner is not well understood. We used coarse-grained molecular dynamics simulations to examine the reversibility of the effects of peptide and cholesterol concentrations as well as a lipid domain-perturbing nanoparticle (C60) on the dynamics and stability of H-Ras lipid-anchor nanoclusters. By comparing results from these simulations with previous observations from the literature, we show that effects of peptide/cholesterol concentrations on the dynamics and stability of H-Ras peptide nanoclusters are reversible. Our results also suggest a correlation between the stabilities of lipid domains and Ras nanoclusters, which is supported by our finding that C60 penetrates into the liquid-disordered domain of the bilayer, destabilizing lipid domains and thereby the stability of the nanoclusters.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Dose-Response Relationship, Drug
  • Lipids / chemistry*
  • Lipids / pharmacology*
  • Molecular Dynamics Simulation
  • Nanoparticles / chemistry
  • Peptides / pharmacology*
  • Protein Binding / drug effects
  • Protein Conformation
  • Protein Stability / drug effects
  • ras Proteins / chemistry*
  • ras Proteins / metabolism*

Substances

  • Lipids
  • Peptides
  • ras Proteins