Biochemical, immunological and kinetic characterization and partial sequence analysis of a thiol proteinase inhibitor from Bubalus bubalis kidney: An attempt targeting kidney disorders

Int J Biol Macromol. 2017 Jan;94(Pt B):819-826. doi: 10.1016/j.ijbiomac.2015.12.084. Epub 2016 Jan 2.

Abstract

In the present study a thiol proteinase inhibitor was isolated from buffalo kidney making use of ammonium sulphate precipitation and gel filtration chromatography on Sephacryl S-100HR column. Purified inhibitor is homogeneous as it displayed a single band in gel electrophoresis both under reducing and non-reducing environment and is of 65KDa as revealed by gel filtration and SDS PAGE. Kinetic studies revealed the presence of reversible accompanied with competitive mode of inhibition; showing maximum efficacy against papain (Ki=2.90×10-4). It was maximally active at pH 8.0 and was stable for a period of 30, 60 and 90 days at 37, 4 and -20°C respectively. Immunological studies confirmed its purity of epitopes as a single precipitin line is obtained in immunodiffusion. N-terminal analysis revealed that it shared a good homology with mouse kidney cystatin as well as with Human Cys C and Cys E thereby advocating its use as a model for various human oriented studies which targets how the kidney cystatin level varies in accordance with various drugs that are currently being used as a target for variety of diseases.

Keywords: Cystatin; N-terminal analysis; Papain.

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Bromelains / antagonists & inhibitors
  • Bromelains / chemistry
  • Buffaloes
  • Cystatins / chemistry*
  • Cystatins / immunology
  • Cystatins / isolation & purification
  • Ficain / antagonists & inhibitors
  • Ficain / chemistry
  • Humans
  • Hydrogen-Ion Concentration
  • Kidney / chemistry*
  • Kidney / immunology
  • Kinetics
  • Mice
  • Molecular Weight
  • Papain / antagonists & inhibitors
  • Papain / chemistry*
  • Protease Inhibitors / chemistry*
  • Protease Inhibitors / immunology
  • Protease Inhibitors / isolation & purification
  • Protein Stability
  • Sequence Alignment
  • Sulfhydryl Compounds / chemistry*

Substances

  • Cystatins
  • Protease Inhibitors
  • Sulfhydryl Compounds
  • Bromelains
  • Papain
  • Ficain