Nitride tuning of lanthanide chromites

Chem Commun (Camb). 2016 Mar 21;52(23):4317-20. doi: 10.1039/c6cc00744a.

Abstract

LnCrO(3-x)N(x) perovskites with Ln = La, Pr and Nd and nitrogen contents up to x = 0.59 have been synthesised through ammonolysis of LnCrO4 precursors. These new materials represent one of the few examples of chromium oxynitrides. Hole-doping through O(2-)/N(3-) anion substitution suppresses the magnetic transition far less drastically than Ln(3+)/M(2+) (M = Ca, Sr) cation substitutions because of the greater covalency of metal-nitride bonds. Hence, nitride-doping is a more benign method for doping metal oxides without suppressing electronic transitions.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chromium / chemistry*
  • Lanthanoid Series Elements / chemistry*
  • Nitrogen / chemistry*

Substances

  • Lanthanoid Series Elements
  • Chromium
  • Nitrogen