The enhanced anti-tissue adhesive effect of injectable pluronic-HA hydrogel by poly(γ-glutamic acid)

Int J Biol Macromol. 2016 Dec;93(Pt B):1603-1611. doi: 10.1016/j.ijbiomac.2016.02.064. Epub 2016 Feb 27.

Abstract

The stability of tissue barrier in physiological condition is a key factor to isolate the damaged site from adjacent tissue for anti-tissue adhesion. Although pluronic or pluronic-hyaluronic acid (HA) hydrogel as an injectable formulation can prevent tissue adhesion at the injection site, the anti-tissue adhesion effect is limited due to its poor stability. Herein, we prepared tissue barrier formulations composed of pluronic F127 (F127) and HA mixture (F127-HA) and the effect of the addition of poly(γ-glutamic acid) (PGA) was characterized. All of F127, HA, and F127-HA mixture showed the poor in vitro residence stability less than 3 days. However, by adding PGA into F127-HA mixture, their stability was significantly enhanced by the control of the molecular weight and concentration of PGA. Thus, F127-HA with 10wt% PGA (2000kDa) showed the long-term stability over 10 days. Similarly, the enhanced stability of F127-HA with PGA resulted in the enhanced and excellent in vivo anti-tissue adhesion effect, evidenced by histological analysis and grading of tissue adhesion. Therefore, F127-HA containing PGA could be applied as an efficient injectable tissue barrier for anti-tissue adhesion.

Keywords: Hyaluronic acid; Hydrogel; Pluronic F127; Poly(γ-glutamic acid); Tissue barrier.

MeSH terms

  • Animals
  • Biocompatible Materials / chemistry*
  • Elastic Modulus
  • Hyaluronic Acid / chemistry
  • Hydrogels / chemistry
  • Mice
  • NIH 3T3 Cells
  • Poloxamer / chemistry
  • Polyglutamic Acid / analogs & derivatives*
  • Polyglutamic Acid / chemistry
  • Rats, Sprague-Dawley
  • Tissue Adhesives / chemistry

Substances

  • Biocompatible Materials
  • Hydrogels
  • Tissue Adhesives
  • poly(gamma-glutamic acid)
  • Poloxamer
  • Polyglutamic Acid
  • Hyaluronic Acid