Identification of E-cadherin signature motifs functioning as cleavage sites for Helicobacter pylori HtrA

Sci Rep. 2016 Mar 17:6:23264. doi: 10.1038/srep23264.

Abstract

The cell adhesion protein and tumour suppressor E-cadherin exhibits important functions in the prevention of gastric cancer. As a class-I carcinogen, Helicobacter pylori (H. pylori) has developed a unique strategy to interfere with E-cadherin functions. In previous studies, we have demonstrated that H. pylori secretes the protease high temperature requirement A (HtrA) which cleaves off the E-cadherin ectodomain (NTF) on epithelial cells. This opens cell-to-cell junctions, allowing bacterial transmigration across the polarised epithelium. Here, we investigated the molecular mechanism of the HtrA-E-cadherin interaction and identified E-cadherin cleavage sites for HtrA. Mass-spectrometry-based proteomics and Edman degradation revealed three signature motifs containing the [VITA]-[VITA]-x-x-D-[DN] sequence pattern, which were preferentially cleaved by HtrA. Based on these sites, we developed a substrate-derived peptide inhibitor that selectively bound and inhibited HtrA, thereby blocking transmigration of H. pylori. The discovery of HtrA-targeted signature sites might further explain why we detected a stable 90 kDa NTF fragment during H. pylori infection, but also additional E-cadherin fragments ranging from 105 kDa to 48 kDa in in vitro cleavage experiments. In conclusion, HtrA targets E-cadherin signature sites that are accessible in in vitro reactions, but might be partially masked on epithelial cells through functional homophilic E-cadherin interactions.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Motifs
  • Antigens, CD
  • Bacterial Proteins / antagonists & inhibitors
  • Bacterial Proteins / metabolism*
  • Cadherins / chemistry
  • Cadherins / genetics
  • Cadherins / metabolism*
  • Cell Line, Tumor
  • Chromatography, High Pressure Liquid
  • Epithelial Cells / cytology
  • Epithelial Cells / metabolism
  • Helicobacter pylori / enzymology*
  • Humans
  • Molecular Sequence Data
  • Peptides / analysis
  • Peptides / chemical synthesis
  • Peptides / metabolism
  • Protein Binding
  • Proteolysis
  • Proteomics
  • Recombinant Fusion Proteins / genetics
  • Recombinant Fusion Proteins / metabolism
  • Serine Proteases / chemistry
  • Serine Proteases / metabolism*
  • Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
  • Substrate Specificity
  • Surface Plasmon Resonance

Substances

  • Antigens, CD
  • Bacterial Proteins
  • CDH1 protein, human
  • Cadherins
  • Peptides
  • Recombinant Fusion Proteins
  • Serine Proteases