Enzymatic characterisation of the immobilised Alcalase to hydrolyse egg white protein for potential allergenicity reduction

J Sci Food Agric. 2017 Jan;97(1):199-206. doi: 10.1002/jsfa.7712. Epub 2016 Apr 19.

Abstract

Background: This study examined technique characteristics of the immobilised Alcalase to hydrolyse egg white protein for potential allergenicity reduction. Alcalase was immobilised covalently on carboxyl-functionalised magnetic beads by carbodiimide activation. The technique characteristics of the immobilised Alcalase were investigated, followed by determining the degrees of hydrolysis (DH), immunoglobulin G (IgG) binding, and IgE binding of the digested egg white protein by immobilised Alcalase.

Results: Enzymatic activity, enzyme loading, and immobilisation yield of the prepared immobilised Alcalase were 20.55 U mg-1 , 925 mg g-1 , and 45%, respectively. Immobilised Alcalase showed maximum activity at pH 8.0 and 60 °C. Compared with free Alcalase, immobilised Alcalase exhibited better thermal and storage stability. Moreover, immobilised Alcalase can be reused 10 times and still maintained 55% of its initial activity. Partial hydrolysis of egg white protein by immobilised Alcalase can effectively reduce IgG and IgE binding of the hydrolysates.

Conclusion: This study indicates that the immobilised Alcalase can be used to hydrolyse continuously egg white protein for potential allergenicity reduction. © 2016 Society of Chemical Industry.

Keywords: egg white protein; hydrolysis; immobilised enzyme; potential allergenicity; technique characteristics.

MeSH terms

  • Egg Proteins / immunology*
  • Egg Proteins / metabolism*
  • Enzyme Stability
  • Enzymes, Immobilized / metabolism*
  • Food Hypersensitivity / prevention & control*
  • Hydrogen-Ion Concentration
  • Hydrolysis
  • Hydrophobic and Hydrophilic Interactions
  • Immunoglobulin E / metabolism
  • Immunoglobulin G / metabolism
  • Protein Hydrolysates / immunology
  • Subtilisins / metabolism*
  • Temperature

Substances

  • Egg Proteins
  • Enzymes, Immobilized
  • Immunoglobulin G
  • Protein Hydrolysates
  • Immunoglobulin E
  • Subtilisins