The water soluble ruthenium(II) organometallic compound [Ru(p-cymene)(bis(3,5 dimethylpyrazol-1-yl)methane)Cl]Cl suppresses triple negative breast cancer growth by inhibiting tumor infiltration of regulatory T cells

Pharmacol Res. 2016 May:107:282-290. doi: 10.1016/j.phrs.2016.03.032. Epub 2016 Mar 30.

Abstract

Ruthenium compounds have become promising alternatives to platinum drugs by displaying specific activities against different cancers and favorable toxicity and clearance properties. Here, we show that the ruthenium(II) complex [Ru(p-cymene)(bis(3,5-dimethylpyrazol-1-yl)methane)Cl]Cl (UNICAM-1) exhibits potent in vivo antitumor effects. When administered as four-dose course, by repeating a single dose (52.4mgkg-1) every three days, UNICAM-1 significantly reduces the growth of A17 triple negative breast cancer cells transplanted into FVB syngeneic mice. Pharmacokinetic studies indicate that UNICAM-1 is rapidly eliminated from kidney, liver and bloodstream thanks to its high hydrosolubility, exerting excellent therapeutic activity with minimal side effects. Immunohistological analysis revealed that the efficacy of UNICAM-1, mainly relies on its capacity to reverse tumor-associated immune suppression by significantly reducing the number of tumor-infiltrating regulatory T cells. Therefore, UNICAM-1 appears very promising for the treatment of TNBC.

Keywords: Anticancer drugs; In vivo tests; Organometallic arene complexes; Ruthenium(II); Triple negative breast cancer; Tumor infiltrating regulatory T cells.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antineoplastic Agents / blood
  • Antineoplastic Agents / pharmacokinetics
  • Antineoplastic Agents / pharmacology
  • Antineoplastic Agents / therapeutic use*
  • Cell Line, Tumor
  • Female
  • Humans
  • Kidney / metabolism
  • Liver / drug effects
  • Liver / metabolism
  • Liver / pathology
  • Mice
  • Organometallic Compounds / blood
  • Organometallic Compounds / pharmacokinetics
  • Organometallic Compounds / pharmacology
  • Organometallic Compounds / therapeutic use*
  • Ruthenium / blood
  • Ruthenium / pharmacokinetics
  • Ruthenium / pharmacology
  • Ruthenium / therapeutic use*
  • T-Lymphocytes, Regulatory / drug effects
  • T-Lymphocytes, Regulatory / immunology
  • Triple Negative Breast Neoplasms / drug therapy*
  • Triple Negative Breast Neoplasms / immunology
  • Triple Negative Breast Neoplasms / metabolism
  • Triple Negative Breast Neoplasms / pathology
  • Tumor Burden / drug effects

Substances

  • Antineoplastic Agents
  • Organometallic Compounds
  • Ruthenium