Equilibrium Phase Behavior of the Square-Well Linear Microphase-Forming Model

J Phys Chem B. 2016 Jul 7;120(26):6178-88. doi: 10.1021/acs.jpcb.6b02167. Epub 2016 May 18.

Abstract

We have recently developed a simulation approach to calculate the equilibrium phase diagram of particle-based microphase formers. Here, this approach is used to calculate the phase behavior of the square-well linear model for different strengths and ranges of the linear long-range repulsive component. The results are compared with various theoretical predictions for microphase formation. The analysis further allows us to better understand the mechanism for microphase formation in colloidal suspensions.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.