Investigation of the Brain Biodistribution of the Lipoprotein-Associated Phospholipase A2 (Lp-PLA2) Inhibitor [18F]GSK2647544 in Healthy Male Subjects

Mol Imaging Biol. 2017 Feb;19(1):153-161. doi: 10.1007/s11307-016-0982-5.

Abstract

Purpose: GSK2647544 is a potent and specific inhibitor of lipoprotein-associated phospholipase A2 (Lp-PLA2), which was in development as a potential treatment for Alzheimer's disease (AD). In order to refine therapeutic dose predictions and confirm brain penetration, a radiolabelled form of the inhibitor, [18F]GSK2647544, was manufactured for use in a positron emission tomography (PET) biodistribution study.

Procedures: [18F]GSK2647544 was produced using a novel, copper iodide (Cu(I)) mediated, [18F]trifluoromethylation methodology. Healthy male subjects (n = 4, age range 34-42) received an oral dose of unlabelled GSK2647544 (100 mg) and after 2 h an intravenous (iv) injection of [18F]GSK2647544 (average injected activity and mass were 106 ± 47 MBq and 179 ± 55 μg, respectively) followed by dynamic PET scans for 120 min. Defined regions of interest (ROI) throughout the brain were used to obtain regional time-activity curves (TACs) and compartmental modelling analysis used to estimate the primary outcome measure, whole brain volume of distribution (VT). Secondary PK and safety endpoints were also recorded.

Results: PET dynamic data were successfully obtained from all four subjects and there were no clinically significant variations of the safety endpoints. Inspection of the TACs indicated a relatively homogenous uptake of [18F]GSK2647544 across all the ROIs examined. The mean whole brain VT was 0.56 (95 % CI, 0.41-0.72). Secondary PK parameters, Cmax (geometric mean) and Tmax (median), were 354 ng/ml and 1.4 h, respectively. Metabolism of GSK2647544 was relatively consistent across subjects, with 20-40 % of the parent compound [18F]GSK2647544 present after 120 min.

Conclusions: The study provides evidence that GSK2647544 is able to cross the blood brain barrier in healthy male subjects leading to a measurable brain exposure. The administered doses of GSK2647544 were well tolerated. Exploratory modelling suggested that a twice-daily dose of 102 mg, at steady state, would provide ~80 % trough inhibition of brain Lp-PLA2 activity.

Trial registration: Clintrials.gov: NCT01924858.

Keywords: Alzheimer’s disease; Biodistribution; GSK2647544; Lp-PLA2; PET; Positron emission tomography.

Publication types

  • Clinical Trial
  • Research Support, Non-U.S. Gov't

MeSH terms

  • 1-Alkyl-2-acetylglycerophosphocholine Esterase / antagonists & inhibitors*
  • 1-Alkyl-2-acetylglycerophosphocholine Esterase / metabolism
  • Adult
  • Animals
  • Brain / metabolism*
  • Fluorine Radioisotopes / chemistry*
  • Humans
  • Image Processing, Computer-Assisted
  • Male
  • Mice
  • Middle Aged
  • Phenyl Ethers / adverse effects
  • Phenyl Ethers / blood
  • Phenyl Ethers / pharmacokinetics*
  • Phenyl Ethers / pharmacology*
  • Pyrimidinones / adverse effects
  • Pyrimidinones / blood
  • Pyrimidinones / pharmacokinetics*
  • Pyrimidinones / pharmacology*
  • Rats
  • Time Factors
  • Tissue Distribution / drug effects

Substances

  • Fluorine Radioisotopes
  • GSK2647544
  • Phenyl Ethers
  • Pyrimidinones
  • 1-Alkyl-2-acetylglycerophosphocholine Esterase

Associated data

  • ClinicalTrials.gov/NCT01924858