Fluorescent and Electroactive Low-Viscosity Tetrazine-Based Organic Liquids

ACS Appl Mater Interfaces. 2016 Aug 10;8(31):19843-6. doi: 10.1021/acsami.6b04677. Epub 2016 Jul 28.

Abstract

New fluorescent molecular liquids with a tetrazine core have been prepared. These compounds remain liquid at least down to -60 °C and display very low viscosities (28 mPa.s for liquid 1, 58 mPa.s for liquid 2). Both compounds remain fluorescent in the condensed phase. For liquid 1, intermolecular quenching is observed to a certain extent, whereas liquid 2 displays similar photophysical properties in dilute solution and in neat film.

Keywords: fluorescence; fluorescent liquids; low-viscosity dyes; molecular liquids; tetrazines.